The structures of fluorene– (H2O)1,2 determined by rotational coherence spectroscopy

Rotational coherence spectroscopy ~RCS!, via time-correlated single photon counting, and two-color resonant two-photon ionization ~R2PI! time-of-flight mass spectrometry, have been used to characterize fluorene–(water)1,2[FL– (H2O)1,2] van der Waals clusters generated in supersonic jets. Rotational coherence traces have been obtained at excitation energies corresponding to several resonant features in the S1\u3c-S0 R2PI spectra of FL– (H2O)1,2 . RCS simulations and diagonalization of the moment of inertia tensor have been used to obtain S1 excited state rotational constants and structures of FL– (H2O)1,2 that are consistent with the experimental rotational coherence traces. The RCS results indicate that: (i) the water molecule in FL–H2O resides above the central five member ring and interacts with both aromatic sites; (ii) the water molecules in FL– (H2O)2 form a water dimer that is most likely oriented along the long axis of fluorene and is hydrogen-bonded to both aromatic sites. The S1\u3c-S0 R2PI spectra of FL– (D2O)1,2 and FL–HDO have also been obtained. The 000 transition is a doublet in the R2PI spectra of FL–H2O, FL–D2O, and a singlet in the R2PI spectrum of FL–HDO. The presence of this doublet in the FL–H2O/D2O spectra, and the absence of such a splitting in the FL–HDO spectrum, is an indication of internal rotation of the water molecule on a potential energy surface that changes upon electronic excitation. Lastly, the use of RCS and time-resolved fluorescence as a tool for assigning features in R2PI spectra that are of ambiguous origin due to fragmentation of higher mass clusters into lower mass channels is demonstrated

Possible male infanticide in wild orangutans and a re-evaluation of infanticide risk

Infanticide as a male reproductive tactic is widespread across mammals, and is particularly prevalent in catarrhine primates. While it has never been observed in wild orangutans, infanticide by non-sire males has been predicted to occur due to their extremely long inter-birth intervals, semi-solitary social structure, and the presence of female counter-tactics to infanticide. Here, we report on the disappearance of a healthy four-month-old infant, along with a serious foot injury suffered by the primiparous mother. No other cases of infant mortality have been observed at this site in 30 years of study. Using photographic measurements of the injury, and information on the behavior and bite size of potential predators, we evaluate the possible causes of this injury. The context, including the behavior of the female and the presence of a new male at the time of the injury, lead us to conclude that the most likely cause of the infant loss and maternal injury was male infanticide. We suggest that in orangutans, and other species where nulliparous females are not preferred mates, these females may be less successful at using paternity confusion as an infanticide avoidance tactic, thus increasing the likelihood of infanticide of their first-born infants.Published versio

Chinese and African migrant entrepreneur's articulation shaped by African agency

Much has been written on the relationship of China and Africa in the past decade. However, the subject of Chinese migrant entrepreneurs in Africa and their articulation with African counterparts was little explored up to the early 2010s. Apparently, this research gap has been closed, as shown by four publications in recent years: three edited volumes and one monography, focusing on this subject. In view of early prejudices on the passive or even disapproving reception of Chinese migrants by Africans, the state of the art underlines the importance and scope of African agency vis à vis Chinese migrant entrepreneurs in Africa. This has been underlined unison in the four books under review. Book review of:(1) Giese, Karsten, Marfaing, Laurence (eds) (2016): Entrepreneurs Africains et Chinois. Les impacts sociaux d’une rencontre particulière. Paris: Karthala. (2) Gadzala, Aleksandra W. (ed) (2015): Africa and China: how Africans and their governments are shaping relations with China. Lanham/Md.: Rowman & Littlefield. (3) Mohan, Giles, Lampert, Ben et al (eds) (2014): Chinese Migrants and Africa's Development: new imperialists or agents of change? London: Zed books. (4) French, Howard W. (2015): China's Second Continent: how a million migrants are building a new empire in Africa. London: Penguin Random House / New York: Knopf.On a beaucoup écrit sur la relation entre la Chine et l'Afrique dans la dernière décennie. Cependant, le sujet des entrepreneurs migrants chinois en Afrique et leur articulation avec leurs homologues africains a été peu exploré jusqu'au début des années 2010. Apparemment, cet écart de recherche a été fermé, comme indiqué par quatre publications au cours des dernières années: trois volumes édités et une monographie, en se concentrant sur ce sujet. Compte tenu des premiers préjugés sur la réception passive ou même désapprobateur des migrants chinois par les Africains, l'état de l'art souligne l'importance et la portée de l'agence africaine vis-à-vis des entrepreneurs migrants chinois en Afrique

Carrier dynamics in α‐Fe2O3 (0001) thin films and single crystals probed by femtosecond transient absorption and reflectivity

Femtosecond transient reflectivity and absorption are used to measure the carrier lifetimes in α‐Fe2O3 thin films and single crystals. The results from the thin films show that initially excited hot electrons relax to the band edge within 300 fs and then recombine with holes or trap within 5 ps. The trapped electrons have a lifetime of hundreds of picoseconds. Transient reflectivity measurements from hematite (α‐Fe2O3)single crystals show similar but slightly faster dynamics leading to the conclusion that the short carrier lifetimes in these materials are due primarily to trapping to Fe d-d states in the band gap. In the hematite single crystal, the transient reflectivity displays oscillations due to the formation of longitudinal acoustic phonons generated following absorption of the ultrashort excitation pulse

Stressed backbone and elasticity of random central-force systems

We use a new algorithm to find the stress-carrying backbone of ``generic'' site-diluted triangular lattices of up to 10^6 sites. Generic lattices can be made by randomly displacing the sites of a regular lattice. The percolation threshold is Pc=0.6975 +/- 0.0003, the correlation length exponent \nu =1.16 +/- 0.03 and the fractal dimension of the backbone Db=1.78 +/- 0.02. The number of ``critical bonds'' (if you remove them rigidity is lost) on the backbone scales as L^{x}, with x=0.85 +/- 0.05. The Young's modulus is also calculated.Comment: 5 pages, 5 figures, uses epsfi

Combinatorial models of rigidity and renormalization

We first introduce the percolation problems associated with the graph theoretical concepts of $(k,l)$-sparsity, and make contact with the physical concepts of ordinary and rigidity percolation. We then devise a renormalization transformation for $(k,l)$-percolation problems, and investigate its domain of validity. In particular, we show that it allows an exact solution of $(k,l)$-percolation problems on hierarchical graphs, for $k\leq l<2k$. We introduce and solve by renormalization such a model, which has the interesting feature of showing both ordinary percolation and rigidity percolation phase transitions, depending on the values of the parameters.Comment: 22 pages, 6 figure

IgM antibody level against proinflammatory bacterial peptidoglycan is inversely correlated with extent of atherosclerotic disease

Objective: Atherosclerosis may lead to acute clinical events by rupture of a vulnerable atherosclerotic plaque. Previously, we demonstrated that peptidoglycan (PGN), a major cell wall component of gram-positive bacteria that induces production of proinflammatory cytokines through TLR2 and CD14, is prevalent in atherosclerotic lesions with histological features associated with plaque vulnerability. We hypothesized that in atherosclerotic patients antibody levels against PGN may differ compared with matched controls. Methods and results: ELISA was performed to measure immunoglobulin levels against PGN in sera of 80 atherosclerotic patients versus 77 control patients with an increased cardiovascular risk, frequency-matched for age, sex and risk factors for atherosclerotic disease. In all patients and controls, intima-media (IMT) thickness was assessed using an array transducer. Significantly lower levels of IgM directed against PGN were found in atherosclerotic patients compared with the control patients without clinically manifested disease (P=0.02). The IgM levels against PGN decreased with increasing mean common carotid IMT thickness (P=0.006). Conclusions: These results show that patients suffering from atherosclerotic disease have decreased IgM levels against PGN. The data suggest that an antibody response against PGN could have a protective effect against the development or activity of atherosclerotic disease

Asia-Pacific ICEMR: Understanding Malaria Transmission to Accelerate Malaria Elimination in the Asia Pacific Region

Gaining an in-depth understanding of malaria transmission requires integrated, multifaceted research approaches. The Asia-Pacific International Center of Excellence in Malaria Research (ICEMR) is applying specifically developed molecular and immunological assays, in-depth entomological assessments, and advanced statistical and mathematical modeling approaches to a rich series of longitudinal cohort and cross-sectional studies in Papua New Guinea and Cambodia. This is revealing both the essential contribution of forest-based transmission and the particular challenges posed by Plasmodium vivax to malaria elimination in Cambodia. In Papua New Guinea, these studies document the complex host–vector–parasite interactions that are underlying both the stunning reductions in malaria burden from 2006 to 2014 and the significant resurgence in transmission in 2016 to 2018. Here we describe the novel analytical, surveillance, molecular, and immunological tools that are being applied in our ongoing Asia-Pacific ICEMR research program